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41.
Three new rock reference samples, Rhyolite JR-3, Gabbro JGb-2 and Hornblendite JH-1 have been prepared by the Geological Survey of Japan for collaborative studies on their chemical composition. Twenty-eight major, minor and trace elements were determined and presented. The results of homogeneity tests showed that all elements are considered to be distributed homogeneously in each reference sample. Geological and mineralogical characteristics are also described.  相似文献   
42.
Single whole crystals of calcic augite from M. Etna, Sicily, which display both sector and oscillatory zoning, have been serially sectioned and the form of the sectors mapped out. The principal intersectorial chemical variation is shown to be that of Ti and Al by as much as 39% (cation %) change in each, and the least variation, that of Ca (showing a 0.77 to 3.20% change). For each of three isochronous surfaces the ratio of Ti∶Al is shown to be individually constant no matter what the sector and this is thought to indicate near equilibrium conditions at the crystal/liquid interface. In addition to sector zoning these crystals display two types of concentric banding, having dimensions of about 0.25 mm, 20 μm. The 20 μm banding is shown to be both optically and chemically oscillated. Relative diffusion rates of cationic species in the melt, and growth rates of crystal faces are thought to play an important role in the formation of the oscillations, and the sector zoning.  相似文献   
43.
Major and trace element compositions of amphibolites and quartzose rocks in the 230-m-thick metamorphic sole underlying the mantle section of the Oman ophiolite in Wadi Tayin area were determined to investigate the chemical characteristics of the hydrous fluid released from subducted amphiboltie-facies slab. The fluid-immobile element compositions indicate that protoliths of these rocks are mid-ocean ridge basalt-like tholeiite and deep-sea chert, which is consistent with the idea that these rocks represent Tethyan oceanic crust overridden during the early, intraoceanic thrusting stage of the Oman ophiolite emplacement. The rare-earth element (REE) and high field-strength element concentrations of the amphibolites show limited variations, within a factor of two except for a few evolved samples, throughout transect of the sole. On the other hand, concentrations of fluid-mobile elements, especially B, Rb, K and Ba, in amphibolites are highly elevated in upper 30 m of the sole (> 600 °C in peak metamorphic temperature), suggesting the equilibration with evolved, B-Rb-K-Ba-rich fluids during prograde metamorphism. The comparison with amphibolites in the lower 150 m (500 to 550 °C) demonstrates that the trace element spectra of the fluids equilibrated with the high-level amphibolites may vary as a function of metamorphic temperature. The fluids are characterized by striking enrichments of B, Rb, K and Ba and moderate to minor enrichments of Sr, Li, Be and Pb. At higher temperature (up to 700 °C), the fluids become considerably enriched in light REE and Nb in addition to the above elements. The estimated trace element spectra of the fluids do not coincide with the compositions of basalts from matured intra-oceanic arcs, but satisfactorily explain the characteristics of the low-Pb andesites and boninites found in the Oman ophiolite. Compositional similarity between the boninites of Oman and other localities suggests that the fluids estimated here well represent the amphibolite-derived fluids involved in the magmatism of immatured, hot, shallow subduction zones.  相似文献   
44.
138Ce/142Ce and 143Nd/144Nd isotope ratios of lunar samples are determined to constrain the petrogenetic differentiation and evolution of the moon. High-precision Ce-Nd isotope data, well-defined Rb-Sr isochrons, and rare earth elements (REE) abundances of lunar samples show that unexpectedly low La/Ce ratios of evolved lunar highland samples are preserved from at least 3.9 Ga. Precise analysis of REE abundances indicates that the low La/Ce ratio results from a depletion of La relative to other REE. This depletion can be seen in pristine KREEP basalts and Mg-suite rocks from 3.85 to 4.46 Ga. As REE abundances of all these samples are controlled by the presence of a KREEP component, the depletion was probably inherited from a late crystallization sequence of the lunar magma ocean related to the production of the original KREEP component.  相似文献   
45.
The ultrahigh-temperature (UHT) metamorphism of the Napier Complex is characterized by the presence of dry mineral assemblages, the stability of which requires anhydrous conditions. Typically, the presence of the index mineral orthopyroxene in more than one lithology indicates that H2O activities were substantially low. In this study, we investigate a suite of UHT rocks comprising quartzo-feldspathic garnet gneiss, sapphirine granulite, garnet-orthopyroxene gneiss, and magnetite-quartz gneiss from Tonagh Island. High Al contents in orthopyroxene from sapphirine granulite, the presence of an equilibrium sapphirine-quartz assemblage, mesoperthite in quartzo-feldspathic garnet gneiss, and an inverted pigeonite-augite assemblage in magnetite-quartz gneiss indicate that the peak temperature conditions were higher than 1,000 °C. Petrology, mineral phase equilibria, and pressure-temperature computations presented in this study indicate that the Tonagh Island granulites experienced maximum P-T conditions of up to 9 kbar and 1,100 °C, which are comparable with previous P-T estimates for Tonagh and East Tonagh Islands. The textures and mineral reactions preserved by these UHT rocks are consistent with an isobaric cooling (IBC) history probably following an counterclockwise P-T path. We document the occurrence of very high-density CO2-rich fluid inclusions in the UHT rocks from Tonagh Island and characterize their nature, composition, and density from systematic petrographic and microthermometric studies. Our study shows the common presence of carbonic fluid inclusions entrapped within sapphirine, quartz, garnet and orthopyroxene. Analysed fluid inclusions in sapphirine, and some in garnet and quartz, were trapped during mineral growth at UHT conditions as 'primary' inclusions. The melting temperatures of fluids in most cases lie in the range of -56.3 to -57.2 °C, close to the triple point for pure CO2 (-56.6 °C). The only exceptions are fluid inclusions in magnetite-quartz gneiss, which show slight depression in their melting temperatures (-56.7 to -57.8 °C) suggesting traces of additional fluid species such as N2 in the dominantly CO2-rich fluid. Homogenization of pure CO2 inclusions in the quartzo-feldspathic garnet gneiss, sapphirine granulite, and garnet-orthopyroxene gneiss occurs into the liquid phase at temperatures in the range of -34.9 to +4.2 °C. This translates into very high CO2 densities in the range of 0.95-1.07 g/cm3. In the garnet-orthopyroxene gneiss, the composition and density of inclusions in the different minerals show systematic variation, with highest homogenization temperatures (lowest density) yielded by inclusions in garnet, as against inclusions with lowest homogenization (high density) in quartz. This could be a reflection of continued recrystallization of quartz with entrapment of late fluids along the IBC path. Very high-density CO2 inclusions in sapphirine associated with quartz in the Tonagh Island rocks provide potential evidence for the involvement of CO2-rich fluids during extreme crustal temperatures associated with UHT metamorphism. The estimated CO2 isochores for sapphirine granulite intersect the counterclockwise P-T trajectory of Tonagh Island rocks at around 6-9 kbar at 1,100 °C, which corresponds to the peak metamorphic conditions of this terrane derived from mineral phase equilibria, and the stability field of sapphirine + quartz. Therefore, we infer that CO2 was the dominant fluid species present during the peak metamorphism in Tonagh Island, and interpret that the fluid inclusions preserve traces of the synmetamorphic fluid from the UHT event. The stability of anhydrous minerals, such as orthopyroxene, in the study area might have been achieved by the lowering of H2O activity through the influx of CO2 at peak metamorphic conditions (>1,100 °C). Our microthermometric data support a counterclockwise P-T path for the Napier Complex.  相似文献   
46.
胶东烟台磁山花岗岩的形成时代及其成矿意义   总被引:3,自引:0,他引:3  
利用激光探针等离子体质谱测年技术(LA-ICP-MS)对胶东烟台磁山花岗岩的锆石进行了U-Pb年龄测定,8粒锆石的年龄为199~149Ma,可分成3组:192~199Ma(3粒)、178~185Ma(2粒)和149~154Ma(3粒),第3组年龄可能代表岩体的最终侵位时代,表明岩体形成于晚侏罗世,为燕山期花岗岩。另外4粒早元古代的继承锆石年龄为2110~2467Ma,平均年龄为2252±41Ma,反映其源岩有早元古代粉子山群的物质。该岩体的形成年龄为探讨南张家金矿的成因提供了重要依据。  相似文献   
47.
The Ediacaran period was one of the most important times for the evolution of life. However, the scarcity of well-preserved outcrops of Ediacaran rocks still leaves ambiguity in decoding ambient surface environmental changes and biological evolution.The Ediacaran strata in South China are almost continuously exposed, comprise mainly carbonate rocks with subordinate black shales and sandstones, and they contain many fossils, suitable for study of environmental and biological changes in the Ediacaran. We conducted drilling through the Doushantuo Fm at four sites in the Three Gorges area to obtain continuous, fresh samples without surface alteration and oxidation. We analyzed 87Sr/86Sr and 88Sr/86Sr ratios of the fresh carbonate rocks, selected on the basis of microscopic observations and the geochemical signatures of Sr contents, Mn/Sr and Rb/Sr ratios, and δ18O values, with a multiple collector-inductively coupled plasma-mass spectrometer (MC-ICP-MS).The chemostratigraphy of the 87Sr/86Sr ratios of the drilled samples displays a smooth curve and two large positive shifts during Ediacaran time. The combination of the detailed chemostratigraphies of δ13C, δ18O and 87Sr/86Sr values and Mn and Fe contents enables us to decode the surface environmental changes and their causes in the Ediacaran. The first large positive excursion of 87Sr/86Sr occurred together with negative δ13C and positive δ18O excursions. The higher 87Sr/86Sr values indicate an enhancement of continental weathering, whereas the positive δ18O excursion suggests global cooling. Global regression due to global cooling enhanced the oxidative decay of exposed marine organic sediments and continental weathering. Accelerated influx of nutrients promoted primary productivity, resulting in oxidation of dissolved organic carbon (DOC), whereas active sulfate reduction due to a higher sulfate influx from the continents caused remineralization of the large DOC, both of which caused a negative δ13C anomaly. The 580 Ma Gaskiers glaciation accounts for the close correlation among the positive 87Sr/86Sr, negative δ13C and positive δ18O excursions.The second large positive shift of 87Sr/86Sr firstly accompanied a positive δ13C excursion, and continued through the Shuram δ13C negative excursion. The positive correlation of δ13C and 87Sr/86Sr values is consistent with an enhanced continental weathering rate due to continental collisions that built Trans-Gondwana mountain chains, and with a higher primary activity due to the enhancement of continental weathering and consequent higher nutrient contents in seawater. The accompanied increase in Mn and Fe contents implies a gradual decline of the seawater oxygen content due to more active aerobic respiration and oxidation of reductive materials flowing in the oceans. In the Shuram excursion, higher 87Sr/86Sr values and a transition from increase to decrease in Mn and Fe contents were accompanied by the large negative δ13C excursion. The higher 87Sr/86Sr values are the first compelling evidence for enhanced continental weathering, which was responsible for the large δ13C anomaly through the remineralization of the DOC by more active sulfate reduction due to a higher sulfate influx. Higher Mn and Fe contents in the early and middle stages of the excursion suggest a decline in the oxygen content of seawater due to oxidative decay of the DOC, whereas in the late stages the decrease in Mn and Fe contents is consistent with oceanic oxygenation.The emergence of Ediacara biota after the Gaskiers glaciation and the prosperity of the latest Ediacaran is concomitant with the formation of more radiogenic seawater with high 87Sr/86Sr values, suggesting that enhanced continental weathering, and the consequent higher influx of nutrients, played an important role in biological evolution.  相似文献   
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Abstract

The effect of the El Niño Southern Oscillation (ENSO) on rainfall characteristics in the tropical peatland areas of Central Kalimantan, Indonesia, is demonstrated. This research used rainfall data collected between 1978 and 2008. The results suggest a relationship between ENSO events and the trend in rainfall observed in the study area. Further analyses show that El Niño events have a stronger effect on the rainfall compared to La Niña events. El Niño events were also correlated to the increase in the number of days with less than 1 mm of rainfall in the dry season. The analysis reveals that the impact of El Niño events on rainfall in dry seasons is intensifying annually. Furthermore, ENSO events are not the only factors affecting rainfall trends in the observed area. Other factors, such as deforestation, may also affect the trend.

Editor Z.W. Kundzewicz

Citation Susilo, G.E., Yamamoto, K., Imai, T., Ishii, Y., Fukami, H., and Sekine, M., 2013. The effect of ENSO on rainfall characteristics in the tropical peatland areas of Central Kalimantan, Indonesia. Hydrological Sciences Journal, 58 (3), 539–548.  相似文献   
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